Wednesday, March 18, 2009

Did Tin Pest Cause Napoleon's Wardrobe Failure?

Blog on Design News: "Peny LeCouteur, co-author of the book book “Napoleon’s Buttons” How 17 Molecules Changed History,” a highly entertaining look at chemical compounds and their impact on the course of history."

“It’s a story that virtually every chemistry student has heard, but we don’t really know if Napoleon’s army actually had buttons made of tin,” she says. 

Though the section on Napoleon’s wardrobe is a mere couple of pages, LeCouteur, a former chemistry professor and now administrator at Capilano College, says that while she was researching the book she was struck by photos of old tin vessels that are now in museums. “What amazed me was that they no longer had that sharp outline to their geometries, which made sense because these objects were exposed to the frigid winters in northern Europe. Victims of tin pest, the outer layers simply turned to powder and sloughed off. “

While it is possible, Lecouteur says, that the same thing could have happened to Napoleon’s buttons. But she says that there is simply not enough evidence to conclude that it did. “There were eyewitness accounts of the weather and you do see paintings that were made of Napoleon and his troops at that time holding old carpets and blankets around themselves to keep warm, so we do know something about the kind of cold they had to endure. But buttons made out of pure tin would have been quite expensive compared to wood or bone. And chemically, tin pest is a very slow process.”

So slow, in fact, that it’s likely Napoleon’s troops would have had to endure some hellishly long winters before their buttons disintegrated. And as one reader shrewdly pointed out, that means they would have had to worry about other things falling off well in advance of their buttons.

Tuesday, March 17, 2009

Fuel cells with liquid tin anodes studied

Fuel Cell Works: "Researchers at DOE's National Energy Technology Laboratory completed the first in a series of studies of electrode behavior for a solid oxide fuel cell operating with a molten tin anode.

The researchers focused on isolating and measuring the various kinetic parameters of the anode: tin oxidation at the anode/ electrolyte interface, oxygen transport through the liquid tin anode, and fuel oxidation/tin reduction at the fuel/anode interface.

Molten metal anodes can consume directly solid fuel sources such as carbon and coal dust, removing the need for a gasifier.

Liquid tin anodes also offer a higher degree of tolerance to coal contaminants that poison conventional nickel-based anodes."

MBK Tin Powder White & Grey

Alibaba.com: "We are manufactured of MBK powder product, specially for Body Odor. This product comfortable with who any one works in outdoor or hard weather / daylight, because this product makes you confidence self although your body swept. Trust us. Because we guarantee, our product is 100% proven and legalcy registered in our country."

What is MBK Tin Powder? MBK Powder is special body odor powder. You can apply this powder under your armpit. I am using it for getting my self confidence. We can apply this powder after shower. Just a little powder that we need to apply under our armpit. Some people said that MBk powder can absorb the swear under your body whenever you have outdoor activity.

I always buy one pack of MBk Powder. And normally I could use it for more than a month. One box of MBK powder contains of 13.6 gram powder (net).
I am not sure how much is the price of one box at this time. It was long time ago since I bought this powder.

In the place where I live now, I could not find it. It is so pity since I like this powder. So whenever I have holiday in my own country, I would like to bring back some boxes. Just to make sure that I have enough stocks for sometimes.

It is easy to use, easy to apply and has no side affect at all. At least that’s what I feel when I was using this powder. And it really gave good result. I have no more body odor during the busy day.Even I had a lot outdoor activities at that time.

Novel lithium ion batteries based on a tin anode and on manganese oxide cathodes

Scopus: "In this paper we report two innovative lithium ion batteries formed by the combination of a nanosized tin anode and a LiNi0.5Mn 1.5O4 or a LiNi0.33 Co0.33Mn 1.33O2 cathode. 

The batteries have a very stable cycling response at a high rate of 1C with an excellent capacity delivery, i.e., 140 mAhg-1 and 175 mAhg-1, respectively. Estimated energy density values are of the order of 150 Whkg-1 for both batteries."